How to filter shipment sections – https://www.wpcargo.com/knowledgebase/how-to-filter-shipment-sections-of-frontend-manager
How to get fields by section – https://www.wpcargo.com/knowledgebase/how-to-get-fields-by-section
Adding Section Before Form Fields
Note: please copy and paste the code in functions.php of your current theme.

function custom_before_wpcfe_shipment_form_fields(){
?>
<div class="col-md-12 mb-5">
<div class="card">
<div class="card-body"><h3>Before Form Fields Section </h3></div>
</div>
</div>
<?php
}
add_action( 'before_wpcfe_shipment_form_fields', 'custom_before_wpcfe_shipment_form_fields', 1, 1 );

Adding Section After Form Fields
function custom_shipment_multipackage_template(){
?>
<div class="col-md-12 mb-5">
<div class="card">
<div class="card-body"><h3>After Form Fields Section </h3></div>
</div>
</div>
<?php
}
add_action( 'after_wpcfe_shipment_form_fields', 'custom_shipment_multipackage_template', 1, 1 );

Adding Section After Shipment History
function custom_after_wpcfe_shipment_history(){
?>
<div class="col-md-12 mb-5">
<div class="card">
<div class="card-body"><h3>After Shipment History Section </h3></div>
</div>
</div>
<?php
}
add_action( 'after_wpcfe_shipment_form_fields', 'custom_after_wpcfe_shipment_history', 20 );

Adding Section After Add Shipment Form
function custom_after_wpcfe_add_shipment_form(){
?>
<div class="card">
<div class="card-body"><h3>After Add Shipment Form </h3></div>
</div>
<?php
}
add_action( 'before_wpcargo_shipment_history', 'custom_after_wpcfe_add_shipment_form', 99 );

Adding Section Before Assign
function custom_before_wpcfe_assign_section(){
?>
<div class="card mb-3">
<div class="card-body">
<h3>Before Assign Section</h3>
</div>
</div>
<?php
}
add_action( 'before_wpcfe_shipment_form_submit', 'custom_before_wpcfe_assign_section', 1 );

Adding Section Before Submit
function custom_before_wpcfe_submit_button(){
?>
<div class="card mb-3">
<div class="card-body">
<h3>Before Submit</h3>
</div>
</div>
<?php
}
add_action( 'before_wpcfe_shipment_form_submit', 'custom_before_wpcfe_submit_button', 70 );